Reversible Metal-Centered Reduction Empowers a Ni-Corrin to Mimic F430
نویسندگان
چکیده
منابع مشابه
A Measurement-Centered Approach to Latency Reduction
Increasing latency on paths through the Internet has a negative impact on latency-sensitive applications such as audio and video conferencing, as well as on the perception of responsiveness of many other applications. Measurement is key to addressing this issue, in two ways. First, the symptoms of excessive latency can be hard to isolate, and the causes obscure: the deployment of passive and ac...
متن کاملMutual control of axial and equatorial ligands: model studies with [Ni]-bacteriochlorophyll-a.
Modification of the metal's electronic environment by ligand association and dissociation in metalloenzymes is considered cardinal to their catalytic activity. We have recently presented a novel system that utilizes the bacteriochlorophyll (BChl) macrocycle as a ligand and reporter. This system allows for charge mobilization in the equatorial plane and experimental estimate of changes in the el...
متن کاملA Highly Reversible Lithium Metal Anode
Lithium metal has shown a lot of promise for use as an anode material in rechargeable batteries owing to its high theoretical capacity. However, it does not meet the cycle life and safety requirements of rechargeable batteries owing to electrolyte decomposition and dendrite formation on the surfaces of the lithium anodes during electrochemical cycling. Here, we propose a novel electrolyte syste...
متن کاملReversible, metal-free hydrogen activation.
Although reversible covalent activation of molecular hydrogen (H2) is a common reaction at transition metal centers, it has proven elusive in compounds of the lighter elements. We report that the compound (C6H2Me3)2PH(C6F4)BH(C6F5)2 (Me, methyl), which we derived through an unusual reaction involving dimesitylphosphine substitution at a para carbon of tris(pentafluorophenyl) borane, cleanly los...
متن کاملMetal (Ni, Co)-Metal Oxides/Graphene Nanocomposites as Multifunctional Electrocatalysts
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 5799 wileyonlinelibrary.com issues associated with energy security and environmental pollution. [ 1–5 ] Oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) are the most crucial electrochemical reactions to realize energy storage and conversion in these technologies. Although Pt-, Ir-, and Ru-ba...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Communications
سال: 2021
ISSN: 1359-7345,1364-548X
DOI: 10.1039/d1cc02945b